Palladium(III) in Synthesis and Catalysis. Academic Article

abstract

• While the organometallic chemistry of Pd in its (0), (+II), and (+IV) oxidation states is well-established, organometallic Pd(III) chemistry remains widely unexplored. Few characterized Pd(III) complexes are known, which has inhibited detailed study of the organometallic chemistry of Pd(III). In this review, the potential roles of both mono- and dinuclear Pd(III) complexes in organometallic chemistry will be discussed. While not widely recognized, Pd in the (+III) oxidation state may play a significant role in a variety of known Pd-catalyzed reactions.

authors

• Powers, David

published proceedings

• Top Organomet Chem

altmetric score

• 3

author list (cited authors)

• Powers, D. C., & Ritter, T.

citation count

• 85

complete list of authors

• Powers, David C||Ritter, Tobias

publication date

• January 2011

publisher

• Springer Nature  Publisher

published in

• Topics in Organometallic Chemistry  Journal

keywords

• Bimetallic Redox Chemistry
• C-h Functionalization
• Metal-metal Bonding
• Pd(iii)

PubMed Central ID

• 21461129

Digital Object Identifier (DOI)

• 10.1007/978-3-642-17429-2_6

start page

• 129

end page

• 156

volume

• 503

URL

• http://dx.doi.org/10.1007/978-3-642-17429-2_6