Reactivity of a Well-Characterized Titananorbornadiene (6-Arene) Complex with Ketones and Aldehydes
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The reaction between the titananorbornadiene complex [(DMSC)Ti(6-1,2,4-(Me3Si)3C6H3)] and ketones or aldehydes were proceeded by insertion of a ketone or aldehyde molecule into a Ti-C bond of 2,5-dioxatitanacyclopentane. The intermediacy of 2-oxatitanacycloheptene species and the formation of 2,5-dioxatitanacyclopentane compounds was also indicated.
author list (cited authors)
Ozerov, O. V., Parkin, S., Brock, C. P., & Ladipo, F. T.
complete list of authors
Ozerov, Oleg V||Parkin, Sean||Brock, Carolyn P||Ladipo, Folami T