Missing link: PCP pincer ligands containing P-N bonds and their Pd complexes
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abstract
New PCP ligands in which the phosphine donor arms are connected to the central aromatic ring via NH moieties and their (PCP)PdCl complexes have been prepared. One such (PCP)PdCl complex was characterized by X-ray diffractometry in the solid state. The (PCP)PdCl complexes are exceptionally robust towards oxygen and water despite the presence of P-N bonds. 2006 Elsevier B.V. All rights reserved.