Decarbonylation of Acetone and Carbonate at a Pincer-Ligated Ru Center Academic Article uri icon

abstract

  • Summary: A Ru center ligated by a pincer bis(o-phos-phinoaryl)amine (PNP) ligand in (PNP)RuH(H 2) is sufficiently electron rich to break C-O and C-C bonds, resulting in the ultimate decarbonylation of hydrocar-bonate and acetone, respectively, to give (PNP)RuH(CO). The decarbonylation of acetone is accompanied by hydrogenolysis of the C-C bonds to produce methane.

published proceedings

  • Organometallics

altmetric score

  • 6

author list (cited authors)

  • elenligil-etin, R., Watson, L. A., Guo, C., Foxman, B. M., & Ozerov, O. V.

citation count

  • 50

complete list of authors

  • Çelenligil-Çetin, Remle||Watson, Lori A||Guo, Chengyun||Foxman, Bruce M||Ozerov, Oleg V

publication date

  • January 2005