Decarbonylation of Acetone and Carbonate at a Pincer-Ligated Ru Center
- Additional Document Info
- View All
Summary: A Ru center ligated by a pincer bis(o-phos-phinoaryl)amine (PNP) ligand in (PNP)RuH(H 2) is sufficiently electron rich to break C-O and C-C bonds, resulting in the ultimate decarbonylation of hydrocar-bonate and acetone, respectively, to give (PNP)RuH(CO). The decarbonylation of acetone is accompanied by hydrogenolysis of the C-C bonds to produce methane.
author list (cited authors)
elenligil-etin, R., Watson, L. A., Guo, C., Foxman, B. M., & Ozerov, O. V.
complete list of authors
Çelenligil-Çetin, Remle||Watson, Lori A||Guo, Chengyun||Foxman, Bruce M||Ozerov, Oleg V