Adaptability of the SiNN Pincer Ligand in Iridium and Rhodium Complexes Relevant to Borylation Catalysis

abstract

• 2015 American Chemical Society. A comparison of Rh and Ir complexes of the SiNN ligand (combining Si-H, amido, and quinoline donors) reveals its great degree of adaptability. The amido donor can function as a boryl group acceptor, and the Si-H/metal interaction is highly variable. In contrast to Ir analogues, complexes of Rh do not catalyze dehydrogenative borylation of terminal alkynes but do act as modest benzene borylation catalysts.

authors

• Ozerov, Oleg

published proceedings

• ORGANOMETALLICS

altmetric score

• 1.5

author list (cited authors)

• Lee, C., Hirscher, N. A., Zhou, J., Bhuvanesh, N., & Ozerov, O. V.

citation count

• 31

complete list of authors

• Lee, Chun-I||Hirscher, Nathanael A||Zhou, Jia||Bhuvanesh, Nattamai||Ozerov, Oleg V

publication date

• July 2015

publisher

• American Chemical Society (ACS)  Publisher

published in

• Organometallics  Journal

keywords

• 34 Chemical Sciences
• 3402 Inorganic Chemistry

Digital Object Identifier (DOI)

• 10.1021/acs.organomet.5b00125

start page

• 3099

end page

• 3102

volume

• 34

issue

• 13

URL

• http%3A%2F%2Fdx.doi.org%2F10.1021%2Facs.organomet.5b00125