Adaptability of the SiNN Pincer Ligand in Iridium and Rhodium Complexes Relevant to Borylation Catalysis Academic Article uri icon

abstract

  • 2015 American Chemical Society. A comparison of Rh and Ir complexes of the SiNN ligand (combining Si-H, amido, and quinoline donors) reveals its great degree of adaptability. The amido donor can function as a boryl group acceptor, and the Si-H/metal interaction is highly variable. In contrast to Ir analogues, complexes of Rh do not catalyze dehydrogenative borylation of terminal alkynes but do act as modest benzene borylation catalysts.

published proceedings

  • Organometallics

altmetric score

  • 1.5

author list (cited authors)

  • Lee, C., Hirscher, N. A., Zhou, J., Bhuvanesh, N., & Ozerov, O. V.

citation count

  • 26

complete list of authors

  • Lee, Chun-I||Hirscher, Nathanael A||Zhou, Jia||Bhuvanesh, Nattamai||Ozerov, Oleg V

publication date

  • March 2015