Retardation of beta-hydrogen elimination in PNP Pincer complexes of Pd

abstract

• A series of new alkyl and alkoxide (FPNP)Pd complexes have been synthesized. The alkyls and alkoxides containing -hydrogens display remarkable thermal stability. Thermal decomposition of (FPNP)PdOEt is very slow in pure C6D6 but is accelerated by the addition of EtOH co-solvent. It is proposed that the -hydrogen elimination from (FPNP)Pd-OCH2R occurs via dissociation of the alkoxide anion. 2006 Elsevier B.V. All rights reserved.

authors

• Ozerov, Oleg

published proceedings

• INORGANICA CHIMICA ACTA

author list (cited authors)

• Fafard, C. M., & Ozerov, O. V.

citation count

• 49

complete list of authors

• Fafard, Claudia M||Ozerov, Oleg V

publication date

• January 2007

publisher

• Elsevier  Publisher

published in

• Inorganica Chimica Acta  Journal

keywords

• Alkoxide Complexes
• Alkyl Complexes
• Elimination
• Palladium
• Pincer

Digital Object Identifier (DOI)

• 10.1016/j.ica.2006.07.067

start page

• 286

end page

• 292

volume

• 360

issue

• 1

URL

• http%3A%2F%2Fdx.doi.org%2F10.1016%2Fj.ica.2006.07.067

user-defined tag

• 7 Affordable and Clean Energy