Triflyloxy-substituted carboranes as useful weakly coordinating anions Academic Article uri icon

abstract

  • New carborane anions carrying one or three triflyloxy substituents are described. The mono-triflyloxy substituted carborane can be halogenated to give pentabromo and decachloro derivatives with preservation of the B-OTf linkage. The use of [HCB11Cl10OTf](-) as a weakly coordinating anion is demonstrated.

author list (cited authors)

  • Press, L. P., McCulloch, B. J., Gu, W., Chen, C., Foxman, B. M., & Ozerov, O. V.

citation count

  • 7

publication date

  • September 2015