The three-body dissociation dynamics of Cl2O at 248 and 193 nm Academic Article uri icon

abstract

  • The photodissociation of Cl2O has been studied at 248 and 193 nm using photofragment translational spectroscopy (PTS) experiments with tunable VUV photoionization detection. The sole products observed were Cl, O and ClO fragments. Based on the derived translational energy distributions for the ClO and Cl photofragments we conclude that at 248 nm 15% of Cl2O excitation results in three-body dissociation. At 193 nm no Cl2 fragments are observed and we conclude that the oxygen atoms arise solely from three-body dissociation. Dissociation geometries derived from forward convolution fitting suggest two qualitatively distinct three-body dissociation pathways: asymmetric concerted dissociation and symmetric concerted dissociation in agreement with recent theoretical predictions. 2009 Elsevier B.V. All rights reserved.

published proceedings

  • JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY

author list (cited authors)

  • Zou, P., Shu, J., & North, S. W.

complete list of authors

  • Zou, Peng||Shu, Jinian||North, Simon W

publication date

  • January 1, 2010 11:11 AM