Vibrational state-selected photodissociation of ClO+ Academic Article uri icon

abstract

  • We report on the UV photodissociation of specific vibrational states (v = 2-45) of ClO + using velocity map ion imaging. The high vibrational states of ClO + are prepared via a double resonant scheme through the ClO (A 2) state and ion-pair states followed by photoionization with a third photon. The absorption of a fourth photon results in photodissociation of the ClO + into two dominant asymptotic channels. The Cl + and O + fragment ion images reveal information on both the energetics of high-lying cation vibrational states and the low-lying dissociative electronic states that correlate to Cl +( 3P) + O( 3P) and Cl( 2P) + O +( 4S) asymptotic channels. We also report ab initio potentials for the bound ClO + and ion-pair states as well as calculations of the ClO + excited states relevant to the photodissociation process. 2012 Elsevier B.V. All rights reserved.

published proceedings

  • CHEMICAL PHYSICS

author list (cited authors)

  • Freeman, C. D., Grubb, M. P., Lane, I. C., & North, S. W.

citation count

  • 2

complete list of authors

  • Freeman, C Daniel||Grubb, Michael P||Lane, Ian C||North, Simon W

publication date

  • January 1, 2012 11:11 AM