MULTIPHOTON IONIZATION OF PHENOL IN NONAQUEOUS SOLUTIONS - CHARACTERIZATION OF THE CATION AND ION MOLECULE CHEMISTRY Academic Article

abstract

• The phenoxy cation has been generated in polar and nonpolar solutions by two-photon ionization of phenol by using 2.5-ns pulses of 266-nm light. The ions have been characterized by pulsed conductivity (ion mobility) measurements and transient absorption spectroscopy with max = 290-300 nm and an estimated extinction coefficient of 1300 M-1 cm-1. The involvement of the phenoxy ion in ion-molecule chemistry with either neutral solute or sovlent molecules has also been observed. The kinetics of these processes as well as a proposed reaction mechanism are presented. 1991 American Chemical Society.

authors

• North, Simon

published proceedings

• JOURNAL OF PHYSICAL CHEMISTRY

altmetric score

• 3

author list (cited authors)

• SIUZDAK, G., NORTH, S., & BELBRUNO, J. J.

citation count

• 29

complete list of authors

• SIUZDAK, G||NORTH, S||BELBRUNO, JJ

publication date

• January 1991

publisher

• American Chemical Society (ACS)  Publisher

published in

• The Journal of physical chemistry  Journal

Digital Object Identifier (DOI)

• 10.1021/j100166a050

start page

• 5186

end page

• 5190

volume

• 95

issue

• 13

URL

• http%3A%2F%2Fdx.doi.org%2F10.1021%2Fj100166a050