Probing the nature of the K-rotor in unimolecular reactions: Scalar and vector correlations in the photodissociation of NCNO
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The photodissociation of NCNO at 520 and 532 nm was examined using transient frequency modulation Doppler spectroscopy in order to study vector and scalar correlations in the dissociation. A small correlation between v and J was observed corresponding to 00(22) bipolar moments ranging from 0.000.02 to -0.030.02 at 532 nm and 0.000.02 to -0.010.02 at 520 nm. These were well described by a helicity unrestricted PST formulation at both wavelengths.
JOURNAL OF CHEMICAL PHYSICS
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McGivern, W. S., & North, S. W.
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