Remarkable regioselectivity in the preparation of the first heterotrimetallic Mo[quadruple bond]W...Cr chain. Academic Article uri icon

abstract

  • Addition of CrCl(2) to the dinuclear synthon MoW(dpa)(4) yields a regioselectively formed heterotrimetallic Mo[quadruple bond]W...Cr chain; computational studies suggest that the polarization of the Mo[quadruple bond]W quadruple bond partially accounts for this unexpected selectivity.

author list (cited authors)

  • Nippe, M., Timmer, G. H., & Berry, J. F

complete list of authors

  • Nippe, Michael||Timmer, George H||Berry, John F

publication date

  • January 1, 2009 11:11 AM