Remarkable regioselectivity in the preparation of the first heterotrimetallic Mo[quadruple bond, length as m-dash]WCr chain Academic Article uri icon

abstract

  • Addition of CrCl(2) to the dinuclear synthon MoW(dpa)(4) yields a regioselectively formed heterotrimetallic Mo[quadruple bond]W...Cr chain; computational studies suggest that the polarization of the Mo[quadruple bond]W quadruple bond partially accounts for this unexpected selectivity.

author list (cited authors)

  • Nippe, M., Timmer, G. H., & Berry, J. F.

citation count

  • 28

publication date

  • January 2009