Chemically reversible four-electron oxidation and reduction utilizing two inorganic functional groups. Academic Article

abstract

• Four-electron oxidation of the quadruply bonded W(2)(II,II) compound W(2)(2,2'-dipyridylamide)(4), 1, results in the formation of a novel, diamagnetic ditungsten terminal oxo compound [W(2)O(2,2'-dipyridylamide)(4)](2+), 2. In contrast to the chemical inertness of mononuclear tungsten oxo species, 2 undergoes a four-electron reduction including oxygen-atom transfer in reactions with excess tri-tert-butylphosphine in acetonitrile to recover 1. This unusual chemically reversible multielectron reactivity is ascribed to the cooperation of W-O and W-W multiple bonding.

authors

• Nippe, Michael

author list (cited authors)

• Nippe, M., Goodman, S. M., Fry, C. G., & Berry, J. F

citation count

• 32

complete list of authors

• Nippe, Michael||Goodman, Samuel M||Fry, Charles G||Berry, John F

publication date

• January 2011

publisher

• American Chemical Society (ACS)  Publisher

published in

• Journal of the American Chemical Society  Journal

keywords

• 2,2'-Dipyridyl
• Amides
• Crystallography, X-Ray
• Models, Molecular
• Oxidation-Reduction
• Tungsten Compounds

PubMed Central ID

• 21319824

Digital Object Identifier (DOI)

• 10.1021/ja1114248

start page

• 2856

end page

• 2859

volume

• 133

issue

• 9

URL

• http%3A%2F%2Fdx.doi.org%2F10.1021%2Fja1114248