Resonantly amplified vibronic symmetry breaking
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Using high-resolution photoelectron spectroscopy coupled to a high brightness synchrotron radiation source, the energy dependence of the vibrational branching ratio for exciting one quantum bending was determined for CO 2 4σ g-1 photoionization. It was found that this transition results from intrachannel coupling.
author list (cited authors)
Rathbone, G. J., Poliakoff, E. D., Bozek, J. D., & Lucchese, R. R.