Complete description of linear molecule photoionization achieved by vector correlations using the light of a single circular polarization Academic Article uri icon

abstract

  • Using the (VA+, Ve, e) vector correlation method enables to perform a complete photoionization experiment involving ground-state molecules, using a single well-defined circular or elliptical polarization of the light. The method is illustrated by the example of photoionization of the NO(X2(c3)) ionic state corresponding to the excitation of the 4 inner-valence shell for which all the complex dipole matrix elements are derived. The results are compared with the calculations performed using the multichannel Schwinger configuration interaction method (MCSCI).

published proceedings

  • JOURNAL OF CHEMICAL PHYSICS

author list (cited authors)

  • Lebech, M., Houver, J. C., Lafosse, A., Dowek, D., Alcaraz, C., Nahon, L., & Lucchese, R. R.

citation count

  • 73

complete list of authors

  • Lebech, M||Houver, JC||Lafosse, A||Dowek, D||Alcaraz, C||Nahon, L||Lucchese, RR

publication date

  • June 2003