MEASUREMENT OF SOLVENT SHIFTS BY RAMAN DIFFERENCE SPECTROSCOPY Academic Article

abstract

• The application of Raman difference spectroscopy for the determination of the small frequency shifts arising from solvent effects has been demonstrated. Data are presented for benzene-carbon disulfide, benzene-pyridine, and acetone-chloroform mixtures. The majority of the solvent shifts measured are less than 1.0 cm1 and these can generally be determined with better than 10% accuracy using a rotating two-compartment liquid cell. The smallest shift measured in this work was 0.06 cm1. While statistical analysis indicates that uncertainties as small as 0.01 cm1 can be obtained in many cases, artifacts may cause apparent shifts up to 0.03 cm1.

authors

• Laane, Jaan

published proceedings

• APPLIED SPECTROSCOPY

author list (cited authors)

• LAANE, J., & KIEFER, W.

citation count

• 27

complete list of authors

• LAANE, J||KIEFER, W

publication date

• May 1981

publisher

• SAGE Publications  Publisher

published in

• APPLIED SPECTROSCOPY  Journal

Digital Object Identifier (DOI)

• 10.1366/0003702814732715

start page

• 267

end page

• 271

volume

• 35

issue

• 3

URL

• http%3A%2F%2Fdx.doi.org%2F10.1366%2F0003702814732715