Hydrogen-substituted osmium silylene complexes: effect of charge localization on catalytic hydrosilation. Academic Article

abstract

• Addition of bulky primary silanes to the osmium benzyl compound, Cp*(iPr3P)OsCH2Ph, afforded two neutral hydrogen-substituted silylene complexes via activation of two Si-H bonds. These species have been structurally characterized, and their reactivity has been examined experimentally and computationally. Comparison of these neutral silylene complexes with their cationic analogue highlights the dramatic influence of charge distribution on the reaction chemistry of metal silylene complexes.

authors

• Hall, Michael

published proceedings

• J Am Chem Soc

author list (cited authors)

• Hayes, P. G., Beddie, C., Hall, M. B., Waterman, R., & Tilley, T. D.

citation count

• 124

complete list of authors

• Hayes, Paul G||Beddie, Chad||Hall, Michael B||Waterman, Rory||Tilley, T Don

publication date

• January 2006

publisher

• American Chemical Society (ACS)  Publisher

published in

• Journal of the American Chemical Society  Journal

keywords

• 0302 Inorganic Chemistry
• 0306 Physical Chemistry (incl. Structural)

PubMed Central ID

• 16402827

Digital Object Identifier (DOI)

• 10.1021/ja057494q

start page

• 428

end page

• 429

volume

• 128

issue

• 2

URL

• http://dx.doi.org/10.1021/ja057494q