THEORETICAL-STUDY OF VIBRATIONAL INTERACTION COORDINATES AND PI-BONDING IN CHROMIUM HEXACARBONYL - COMPARISON WITH COBALT HEXACYANIDE AND NICKEL TETRACARBONYL Academic Article uri icon

abstract

  • Chromium hexacarbonyl has been extensively studied, both experimentally and theoretically, as a model system for transition-metal-carbon monoxide bonding. The near-zerovalent carbonyl complexes known suggest a synergistic effect, i.e., L donation balanced by M L acceptance. Values for these parameters are not readily accessible experimentally, and their magnitudes and relative importance are still being argued in the literature today. 1980, American Chemical Society. All rights reserved.

published proceedings

  • INORGANIC CHEMISTRY

author list (cited authors)

  • SHERWOOD, D. E., & HALL, M. B.

citation count

  • 23

complete list of authors

  • SHERWOOD, DE||HALL, MB

publication date

  • June 1980