THEORETICAL STUDY OF GEOMETRY OF PH3, PF3 AND THEIR GROUND IONIC STATES
Academic Article
Overview
Research
Identity
Additional Document Info
Other
View All
Overview
abstract
The geometries of PH3, PF3and their ground ionic states have been calculated using ab initio SCFMO wavefunctions. All four species are found to be pyramidal, the calculated barriers to inversion being sensitive to the inclusion of d functions in the basis. The calculated potential energy diagrams are found to offer a satisfactory interpretation of the high resolution low energy photoelectron spectra of these molecules.