PI/SIGMA EQUILIBRIA IN METAL-COMPLEXES OF ORGANIC CARBONYL-COMPOUNDS - SYNTHESIS AND STRUCTURE OF CHIRAL RHENIUM COMPLEXES [(ETA-5-C5H5)RE(NO)(PPH3)(O = CHAR)]X
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/ ratios of > 96: < 4 to 15:85 (at 299 K) occur in the complexes 1, depending on the aryl substituents. Aside from this strong electronic effect, marked solvent and temperature effects could also be detected. These findings are of great importance for an understanding of the bonding behavior of adducts of carbonyl compounds and metalcomplex fragments. (Figure Presented.) Copyright 1990 by VCH Verlagsgesellschaft mbH, Germany