ISOMERIZATION OF DIASTEREOISOMERIC ALKENE COMPLEXES OF THE FORMULA [(ETA-5-C5H5)RE(NO)(PPH3)(H2C=CHR)]+ - THE ALKENE ENANTIOFACE BOUND TO THE METAL CAN FLIP WITHOUT ALKENE DISSOCIATION Academic Article uri icon

abstract

  • Deuterium labelling experiments show that the title reaction is intramolecular, and does not proceed by rotation of the =CHR terminus; a mechanism involving a C-H ' bond complex' is proposed.

published proceedings

  • JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS

author list (cited authors)

  • PENG, T. S., & GLADYSZ, J. A.

citation count

  • 5

complete list of authors

  • PENG, TS||GLADYSZ, JA

publication date

  • December 1990