Reactions of organorhenium complexes (η5-C5H5)Re(NO)(PPh3)(CH2R) with Ph3C+ PF6-; analysis of the energetics of α-hydride abstraction
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Reactions of Ph3C+ PF6- with rhenium alkyl complexes (η5-C5H5)-Re(NO) (PPh3)(CH2R) (R = phenyl, n-alkyl) give rhenium alkylidene complexes sc-[(η5-C5H5)Re(NO)(PPh3)=(CHR)]+ PF6-. Modifications in the energy-reaction-coordinate diagrams for these transformations are made on the basis of new data on the relative stabilities of the Re-Cα rotamers of the starting materials. © 1986.
author list (cited authors)
Georgiou, S., & Gladysz, J. A.