REACTIONS OF ORGANORHENIUM COMPLEXES (ETA-5-C5H5)RE(NO)(PPH3)(CH2R) WITH PH3C+PF6- - ANALYSIS OF THE ENERGETICS OF ALPHA-HYDRIDE ABSTRACTION Academic Article uri icon

abstract

  • Reactions of Ph3C+ PF6- with rhenium alkyl complexes (5-C5H5)-Re(NO) (PPh3)(CH2R) (R = phenyl, n-alkyl) give rhenium alkylidene complexes sc-[(5-C5H5)Re(NO)(PPh3)=(CHR)]+ PF6-. Modifications in the energy-reaction-coordinate diagrams for these transformations are made on the basis of new data on the relative stabilities of the Re-C rotamers of the starting materials. 1986.

published proceedings

  • TETRAHEDRON

author list (cited authors)

  • GEORGIOU, S., & GLADYSZ, J. A.

citation count

  • 25

complete list of authors

  • GEORGIOU, S||GLADYSZ, JA

publication date

  • January 1986