MECHANISM OF EQUILIBRATION OF DIASTEREOMERIC RHENIUM AMIDE COMPLEXES OF THE FORMULA (ETA-5-C5H5)RE(NO)(PPH3)(NHCHRR') - RHENIUM VS CARBON EPIMERIZATION Academic Article uri icon

abstract

  • Amide complexes (SR)- and (SS)-(5-C5H5)-Re(NO)(PPh3)(NHCH(CH3)C6H5) epimerize at rhenium (3260 C) by a mechanism involving initial and rate-determining PPh3 dissociation. Anchimeric assistance of the amide ligand lone pair and an intermediate with a planar, trigonal rhenium are proposed. 1990, American Chemical Society. All rights reserved.

published proceedings

  • ORGANOMETALLICS

author list (cited authors)

  • DEWEY, M. A., & GLADYSZ, J. A.

citation count

  • 10

complete list of authors

  • DEWEY, MA||GLADYSZ, JA

publication date

  • April 1990