TOWARDS ONE-DIMENSIONAL CARBON WIRES CONNECTING SINGLE METAL CENTERS - A CUMULENIC C-5 CHAIN THAT MEDIATES CHARGE-TRANSFER BETWEEN RHENIUM AND MANGANESE TERMINI Academic Article uri icon

abstract

  • The longest Cn bridge known between two single metal centers is found in the bimetallic complex 1. The structure of 1 is best described by the cumulene resonance form +ReCCCCCMn. A very intense rheniumtomanganese charge transfer band at 480 nm ( = 60 500M1 cm1) suggests that the C5 ligand acts as a molecular wire. Counterion: BF4 (Figure Presented.) Copyright 1994 by VCH Verlagsgesellschaft mbH, Germany

published proceedings

  • ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

author list (cited authors)

  • WENG, W. G., BARTIK, T., & GLADYSZ, J. A.

citation count

  • 100

complete list of authors

  • Weng, Weiging||Bartik, Tamás||Gladysz, John A

publication date

  • November 1994

publisher