A NEW FORM OF COORDINATED CARBON - A C3 CHAIN THAT IS ANCHORED BY A TRANSITION-METAL ON EACH END AND SPANNED BY A 1/3 Academic Article uri icon

abstract

  • A trirhenium carbene complex containing a C3OMe core, prepared from [Re]CCLi, [Re2(CO)10], and Me3OBF4, leads to complex 1 after abstraction of the methoxy group with BF3 and skeletal rearrangement. According to Xray crystal structure analysis, 1 exists predominantly as the resonance structure shown on the right. [Re] = (5C5Me5)Re(NO)(PPh3). (Figure Presented.) Copyright 1993 by VCH Verlagsgesellschaft mbH, Germany

published proceedings

  • ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH

author list (cited authors)

  • WENG, W. Q., ARIF, A. M., & GLADYSZ, J. A.

citation count

  • 32

complete list of authors

  • WENG, WQ||ARIF, AM||GLADYSZ, JA

publication date

  • June 1993

publisher