NOVEL HETEROCYCLIC RING-SYSTEMS CONTAINING HEAVIER GROUP-13 ELEMENTS
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The reactivities of the new dihydrides, [2,6-(Me2NCH2)2C6H3]MH2 (M = Al, Ga), and the bis-azide, [2,6-(Me2NCH2)2C6H3]Ga(N3)2 have been investigated. The indium tetramer, [InC(SiMe3)3]4, has been prepared via the metathetical reaction of LiC(SiMe3)3.2 THF with InCl. The first neutral galla and indacyclopentadienes have been synthesized by treatment of the zirconacycle, (5-C5H5)2 Zr(C4Me4) with ArMC12 (Ar = 2,4,6-1-Bu3c6H2;M= Ga, In). 1994, Taylor & Francis Group, LLC. All rights reserved.