A Single-Chain Magnet Tape Based on Hexacyanomanganate(III).
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abstract
The tape-like chain {[(tptz)Mn(II) (H2 O)Mn(III) (CN)6 ]2 Mn(II) (H2 O)2 }n 4nMeOH2nH2 O based on the anisotropic building block hexacyanomanganate(III) exhibits long-range magnetic ordering below 5.1K as well as single-chain magnetic behavior at lower temperatures with an effective energy barrier of 40.5(7)K.