NOVEL STRATEGIES FOR THE SYNTHESIS AND CRYSTALLIZATION OF ELECTROPHILIC DINUCLEAR CATIONS - SOLUTION AND SOLID-STATE PROPERTIES OF [RE2(NCCH3)10][MO6O19]2 Academic Article uri icon

abstract

  • An attractive route to mixedvalent metal oxides has been developed from the observation that on slow heating 1 completely loses its acetonitrile ligands at temperatures below 350 C and is transformed into an oxide containing MoVI and Re in two oxidation states. Salt 1 is prepared surprisingly simply according to Equation (a) and shows unexpected electronacceptor properties, which makes it a potential source of a naked Re24+ ion. The structural parameters of the cation of 1 point to a ReRe triple bond, although no strong or donors stabilize the system. (Formula Presented.) Copyright 1992 by VCH Verlagsgesellschaft mbH, Germany

published proceedings

  • ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH

author list (cited authors)

  • BERNSTEIN, S. N., & DUNBAR, K. R.

citation count

  • 29

complete list of authors

  • BERNSTEIN, SN||DUNBAR, KR

publication date

  • October 1992

publisher