Paramagnetic transition metal complexes with sigma-bonded tetracyanoethylene (TCNE)
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Mono- and dimetallic building blocks are being studied in chargetransfer reactions with organic Ji-acceptors such as TCNE to form zero-, one-, and two-dimensional hybrid donor/acceptor compounds. In particular, tetracarboxylate-bridged dinuclear and solvated 3d mononuclear complexes with CT-bonded TCNE ligands are being investigated with regards to their variable temperature magnetic behavior. Results of experiments with dimolybdenum, diruthenium and vanadium complexes are discussed. 1995, Taylor & Francis Group, LLC. All rights reserved.