AN UNUSUAL HETEROBIMETALLIC COMPOUND WITH A RHODIUM(I)-ETA-4-ARENE INTERACTION Academic Article uri icon

abstract

  • The synthesis, structure, and spectroscopic properties of the unusual heterobimetallic complex [(cod)RhCo(TMPP-O)2][BF4]2 (1) are described (cod = 1,5-cyclooctadiene; TMPP = tris(2,4,6-trimethoxyphenyl)phosphine; TMPP-O = [P(C6H2(OMe)3)2(C6H2(OMe)2O)]). The structure of 1 consists of a sixcoordinate Co(III) center in which the phenoxide oxygens are in a trans disposition, with a Rh(I) center being coordinated to the diene molecule in two cis positions and in an 4 bonding mode to one of the demethylated phenyl rings of the TMPP ligand. 1993, American Chemical Society. All rights reserved.

published proceedings

  • ORGANOMETALLICS

author list (cited authors)

  • DUNBAR, K. R., & QUILLEVERE, A.

citation count

  • 18

complete list of authors

  • DUNBAR, KR||QUILLEVERE, A

publication date

  • March 1993