[(RE2CL4(DPPM)2)2(MU-TCNQ)], A NOVEL CHARGE-TRANSFER COMPLEX DERIVED FROM A DONOR WITH A METAL-METAL MULTIPLE BOND Academic Article uri icon

abstract

  • Black crystals of the title complex are obtained by slow diffusion of THF solutions of [Re2Cl4, (dppm)2] (ReRe) and tetracyanoquinodimethane (TCNQ). Although their conductivity is only ca. 105 S cm1, the magnetic and structural features of this charge transfer complex are remarkable. The bridging of two metal complexes by a TCNQ unit is without precedent. The concept of using metalmetal multiplebond systems as donors for inorganic/organic CT complexes appears viable. Copyright 1991 by VCH Verlagsgesellschaft mbH, Germany

published proceedings

  • ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH

author list (cited authors)

  • BARTLEY, S. L., & DUNBAR, K. R.

citation count

  • 45

complete list of authors

  • BARTLEY, SL||DUNBAR, KR

publication date

  • April 1991

publisher