Strong Direct Magnetic Coupling in a Dinuclear Co(II) Tetrazine Radical Single-Molecule Magnet.
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abstract
The ligand-centered radical complex [(CoTPMA)2 --bmtz(.-) ](O3 SCF3 )3 CH3 CN (bmtz=3,6-bis(2'-pyrimidyl)-1,2,4,5-tetrazine, TPMA=tris-(2-pyridylmethyl)amine) has been synthesized from the neutral bmtz precursor. Single-crystal X-ray diffraction studies have confirmed the presence of the ligand-centered radical. The Co(II) complex exhibits slow paramagnetic relaxation in an applied DC field with a barrier to spin reversal of 39K. This behavior is a result of strong antiferromagnetic metal-radical coupling combined with positive axial and strong rhombic anisotropic contributions from the Co(II) ions.