Synthesis and structure of the distorted octahedral palladium(II) complex [Pd(tmpp)2][BF4]2[tmpp = tris(2,4,6-trimethoxyphenyl)phosphine] Academic Article uri icon

abstract

  • The brick-red PdII complex [Pd(tmpp)2][BF 4]2 is isolated from the reaction of [Pd(NCCH 3)4][BF4]2 and tmpp (tris(2,4,6-trimethoxyphenyl)phosphine) (2 equiv.) in acetone at -44C; the new phosphine compound constitutes a rare example of a distored octahedral PdII compound and exhibits the shortest Pd-Lax distances reported to date for six-coordinate PdII complexes.

published proceedings

  • Journal of the Chemical Society, Chemical Communications

author list (cited authors)

  • Dunbar, K. R., & Sun, J.

citation count

  • 41

complete list of authors

  • Dunbar, Kim R||Sun, Jui-Sui

publication date

  • January 1994