SYNTHESIS AND STRUCTURE OF THE DISTORTED OCTAHEDRAL PALLADIUM(II) COMPLEX [PD(TMPP)(2)][BF4](2) [TMPP NUMBER TRIS(2.4,6-TRIMETHOXYPHENYL)PHOSPHINE] Academic Article uri icon

abstract

  • The brick-red PdII complex [Pd(tmpp)2][BF 4]2 is isolated from the reaction of [Pd(NCCH 3)4][BF4]2 and tmpp (tris(2,4,6-trimethoxyphenyl)phosphine) (2 equiv.) in acetone at -44C; the new phosphine compound constitutes a rare example of a distored octahedral PdII compound and exhibits the shortest Pd-Lax distances reported to date for six-coordinate PdII complexes.

published proceedings

  • JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS

author list (cited authors)

  • DUNBAR, K. R., & SUN, J. S.

citation count

  • 41

complete list of authors

  • DUNBAR, KR||SUN, JS

publication date

  • December 1994