Regioselective 12 CO/ 13CO exchange activity of a mixed-valent Fe(ii)Fe(i) model of the H ox state of [FeFe]-hydrogenase Academic Article uri icon

abstract

  • A mixed-valent Fe(ii)Fe(i) model of the H(ox) state of [FeFe]-hydrogenase is shown, under certain conditions, to exhibit regioselective (12)CO/(13)CO exchange activity similar to that observed for H(ox).

author list (cited authors)

  • Thomas, C. M., Liu, T., Hall, M. B., & Darensbourg, M. Y.

citation count

  • 23

publication date

  • February 2008