Regioselective (12)CO/(13)CO exchange activity of a mixed-valent Fe(ii)Fe(i) model of the H(ox) state of [FeFe]-hydrogenase. Academic Article

abstract

• A mixed-valent Fe(ii)Fe(i) model of the H(ox) state of [FeFe]-hydrogenase is shown, under certain conditions, to exhibit regioselective (12)CO/(13)CO exchange activity similar to that observed for H(ox).

authors

• Darensbourg, Marcetta
• Hall, Michael

published proceedings

• Chem Commun (Camb)

author list (cited authors)

• Thomas, C. M., Liu, T., Hall, M. B., & Darensbourg, M. Y.

citation count

• 26

complete list of authors

• Thomas, Christine M||Liu, Tianbiao||Hall, Michael B||Darensbourg, Marcetta Y

publication date

• April 2008

publisher

• Royal Society of Chemistry (RSC)  Publisher

published in

• Chemical Communications  Journal

keywords

• Carbon Isotopes
• Carbon Monoxide
• Ferrous Compounds
• Hydrogenase
• Iron-sulfur Proteins
• Ligands
• Molecular Conformation
• Oxidation-Reduction
• Stereoisomerism

PubMed Central ID

• 18354800

Digital Object Identifier (DOI)

• 10.1039/b719559a

start page

• 1563

end page

• 1565

volume

• 0

issue

• 13

URL

• http://dx.doi.org/10.1039/b719559a