AXIAL LIGATION OF DIAZACYCLOOCTANENICKEL AND DIAZACYCLOOCTANEZINC COMPLEXES Academic Article

abstract

• Thanks to the unusual folding of the diazacyclooctane ligand, which normally blocks an axial position of the metal center, the paramagnetic, blue nickel complex 1 containing a hexacoordinate central Ni atom could be synthesized. In the crystal the O atom of the carboxyl group not coordinated to the Ni center participates in hydrogen bonding with water molecules to form a threedimensional network. (Figure Presented.) Copyright 1993 by VCH Verlagsgesellschaft mbH, Germany

authors

• Darensbourg, Marcetta

published proceedings

• ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH

author list (cited authors)

• GOODMAN, D. C., TUNTULANI, T., FARMER, P. J., DARENSBOURG, M. Y., & REIBENSPIES, J. H.

citation count

• 36

complete list of authors

• GOODMAN, DC||TUNTULANI, T||FARMER, PJ||DARENSBOURG, MY||REIBENSPIES, JH

publication date

• January 1993

publisher

• Wiley  Publisher

published in

• Angewandte Chemie - International Edition  Journal

Digital Object Identifier (DOI)

• 10.1002/anie.199301161

start page

• 116

end page

• 118

volume

• 32

issue

• 1

URL

• http%3A%2F%2Fdx.doi.org%2F10.1002%2Fanie.199301161