THE USE OF ION-PAIRING PHENOMENA IN THE ASSIGNMENT OF NU-(CO) IR BANDS OF PV(CO)5-
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abstract
The interaction of a sodium cation with the trans-CO oxygen of PV(CO)5- (P P(OPh)3, PPh3, P(n-Bu)3) had a major effect on the vibrational mode that is primarily comprised of that CO group and removed the accidental degeneracy of A11 and E v(C0) frequencies. 1981.