The use of ion-pairing phenomena in the assignment of v(co) ir bands of pv(co)5- Academic Article uri icon


  • The interaction of a sodium cation with the trans-CO oxygen of PV(CO)5- (P P(OPh)3, PPh3, P(n-Bu)3) had a major effect on the vibrational mode that is primarily comprised of that CO group and removed the accidental degeneracy of A11 and E v(C0) frequencies. © 1981.

author list (cited authors)

  • Darensbourg, M. Y., & Hanckel, J. M.

citation count

  • 20

publication date

  • September 1981