THE HCR(CO)5- ANION uri icon

abstract

  • The hydridochromium pentacarbonyl anion, HCr(CO)5-, has been isolated and spectroscopically defined as its Et4N+ and Ph4As+ salts. Its great tendency to bind to transition-metal Lewis acids such as [M(CO)5] (M = Mo, W) and [Mo- (PPh3)(CO)4] has allowed for an efficient clean synthesis of heterobinuclear bridging hydride complexes. 1981, American Chemical Society. All rights reserved.

published proceedings

  • INORGANIC CHEMISTRY

author list (cited authors)

  • DARENSBOURG, M. Y., & DEATON, J. C.

citation count

  • 31

complete list of authors

  • DARENSBOURG, MY||DEATON, JC

publication date

  • June 1981