ADDITION OF ACRYLONITRILE TO ANIONIC TRANSITION-METAL HYDRIDES - AN IONIC MODEL FOR HOMOGENEOUS OLEFIN PROCESSES Academic Article

abstract

• The anionic transition metal hydrides, HM(CO)4L- (M = Cr, W; L = CO, P(OMe)3) reacted with acrylonitrile and other activated olefins to yield thermally stable addition products, CH3CH(X)M(CO)4L-. Kinetic data and electronic substituent effects indicated an associative hydride transfer mechanism. 1981.

authors

• Darensbourg, Marcetta

published proceedings

• TETRAHEDRON LETTERS

author list (cited authors)

• DARENSBOURG, M. Y., FLORIS, B., & YOUNGDAHL, K. A.

citation count

• 3

complete list of authors

• DARENSBOURG, MY||FLORIS, B||YOUNGDAHL, KA

publication date

• January 1989

publisher

• Elsevier  Publisher

published in

• Tetrahedron Letters: the international journal for the rapid publication of all preliminary communications in organic chemistry  Journal

keywords

• 34 Chemical Sciences
• 3402 Inorganic Chemistry

Digital Object Identifier (DOI)

• 10.1016/S0040-4039(00)99578-9

start page

• 1781

end page

• 1784

volume

• 30

issue

• 14

URL

• http://dx.doi.org/10.1016/s0040-4039(00)99578-9