ADDITION OF ACRYLONITRILE TO ANIONIC TRANSITION-METAL HYDRIDES - AN IONIC MODEL FOR HOMOGENEOUS OLEFIN PROCESSES Academic Article uri icon

abstract

  • The anionic transition metal hydrides, HM(CO)4L- (M = Cr, W; L = CO, P(OMe)3) reacted with acrylonitrile and other activated olefins to yield thermally stable addition products, CH3CH(X)M(CO)4L-. Kinetic data and electronic substituent effects indicated an associative hydride transfer mechanism. 1981.

published proceedings

  • TETRAHEDRON LETTERS

author list (cited authors)

  • DARENSBOURG, M. Y., FLORIS, B., & YOUNGDAHL, K. A.

citation count

  • 3

complete list of authors

  • DARENSBOURG, MY||FLORIS, B||YOUNGDAHL, KA

publication date

  • January 1989