Nickel mediated sulfur-selenium and sulfur-sulfur bond formation
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abstract
Electrophilic addition of the PhSeCl to a nickel dithiolate yields S,S'- bis(phenylselenenyl-N,N'-bis(mercaptoethyl)-1,5-diazacyclooctane nickel(II) dichloride and a dimeric, intermolecular bis-disulfide which results from ligand oxidation.