Nickel mediated sulfur–selenium and sulfur–sulfur bond formation Academic Article uri icon

abstract

  • Electrophilic addition of the PhSeCl to a nickel dithiolate yields S,S'- bis(phenylselenenyl-N,N'-bis(mercaptoethyl)-1,5-diazacyclooctane nickel(II) dichloride and a dimeric, intermolecular bis-disulfide which results from ligand oxidation.

author list (cited authors)

  • Lai, C., Reibenspies, J. H., & Darensbourg, M. Y.

citation count

  • 10

publication date

  • January 1999