REACTIONS OF ORGANOLITHIUM AND GRIGNARD-REAGENTS WITH CYCLOPENTADIENYLIRON TRICARBONYL CATION AND ITS DERIVATIVES Academic Article

abstract

• Reactions of CH3Li, C6H5Li, and C6H5CH2MgCl with [(C5H5)Fe(CO)2Y]+-[B(C6H5)4]- [Y Co, P(C6H5)3, and CS] have been investigated. The organolithium reagents used act either as reducing agents or as nucleophilic reagents towards the cyclopentadienyliron tricarbonyl cation and its thiocarbonyl analogue. Benzyl-magnesium chloride reacts with the cyclopentadienyl ring of [(C5H5)Fe(CO)3]+ and [(C5H5)Fe(CO)2P(C6H5)3]+ producing neutral cyclopentadiene complexes. 1972.

authors

• Darensbourg, Marcetta

published proceedings

• JOURNAL OF ORGANOMETALLIC CHEMISTRY

author list (cited authors)

• DARENSBOURG, M. Y.

citation count

• 19

complete list of authors

• DARENSBOURG, MY

publication date

• May 1972

publisher

• Elsevier  Publisher

published in

• Journal of Organometallic Chemistry  Journal

keywords

• 34 Chemical Sciences
• 3402 Inorganic Chemistry

Digital Object Identifier (DOI)

• 10.1016/S0022-328X(00)81370-4

start page

• 133

end page

• +

volume

• 38

issue

• 1