Carbon Monoxide and Cyanide Ligands in a Classical Organometallic Complex Model for Fe-Only Hydrogenase. Academic Article

abstract

• The Fe(I) organometallic complex [(-SCH(2)CH(2)CH(2)S)Fe(2)(CO)(6)] provides a structural model for the cyano-carbonyl diiron site of Fe-only hydrogenase as characterized by X-ray crystallography (the picture shows the structure (black) of the model overlaid with that of the Fe-Fe dimetallic site in the hydrogenase isolated from Desulfovibrio desulfuricans). Cyanide substitution of CO occurs readily and provides spectroscopic references for the active site.

authors

• Darensbourg, Marcetta

published proceedings

• Angew Chem Int Ed Engl

altmetric score

• 3

author list (cited authors)

• Lyon, E. J., Georgakaki, I. P., Reibenspies, J. H., & Darensbourg, M. Y.

citation count

• 363

complete list of authors

• Lyon, EJ||Georgakaki, IP||Reibenspies, JH||Darensbourg, MY

publication date

• November 1999

publisher

• Wiley  Publisher

published in

• Angewandte Chemie International Edition  Journal

keywords

• Bioinorganic Chemistry
• C Ligands
• Dinuclear Complexes
• Enzyme Models

PubMed Central ID

• 10556894

Digital Object Identifier (DOI)

• 10.1002/(SICI)1521-3773(19991102)38:21<3178::AID-ANIE3178>3.0.CO;2-4

start page

• 3178

end page

• 3180

volume

• 38

issue

• 21

URL

• http%3A%2F%2Fdx.doi.org%2F10.1002%2F%28sici%291521-3773%2819991102%2938%3A21%253C3178%3A%3Aaid-anie3178%253E3.0.co%3B2-4