OXYGEN-EXCHANGE REACTIONS OF CATIONIC CARBONYL DERIVATIVES OF MANGANESE AND RHENIUM WITH H-2 O-18 AND RELATED PROCESSES Academic Article uri icon

abstract

  • Reactions proposed to involve the intermediacy of metal species containing the hydroxycarbonyl group, [MCOOH], are reviewed. Particular attention is given to reversible reactions of Group VIIb metal carbonyl derivatives with isotopically labelled water, which presumably proceeds via a [MCOOH] intermediate, to afford oxygen labelled metal carbonyl derivatives. The current status of the scope and mechanistic details of this oxygenexchange reaction is summarized. Copyright 1976 WILEYVCH Verlag GmbH & Co. KGaA, Weinheim

published proceedings

  • ISRAEL JOURNAL OF CHEMISTRY

author list (cited authors)

  • DARENSBOURG, D. J.

citation count

  • 11

complete list of authors

  • DARENSBOURG, DJ

publication date

  • January 1977

publisher