OXYGEN-EXCHANGE REACTIONS OF CATIONIC CARBONYL DERIVATIVES OF MANGANESE AND RHENIUM WITH H-2 O-18 AND RELATED PROCESSES

abstract

• Reactions proposed to involve the intermediacy of metal species containing the hydroxycarbonyl group, [MCOOH], are reviewed. Particular attention is given to reversible reactions of Group VIIb metal carbonyl derivatives with isotopically labelled water, which presumably proceeds via a [MCOOH] intermediate, to afford oxygen labelled metal carbonyl derivatives. The current status of the scope and mechanistic details of this oxygenexchange reaction is summarized. Copyright 1976 WILEYVCH Verlag GmbH & Co. KGaA, Weinheim

authors

• Darensbourg, Donald

published proceedings

• ISRAEL JOURNAL OF CHEMISTRY

author list (cited authors)

• DARENSBOURG, D. J.

citation count

• 11

complete list of authors

• DARENSBOURG, DJ

publication date

• January 1977

publisher

• Wiley  Publisher

published in

• Israel Journal of Chemistry  Journal

Digital Object Identifier (DOI)

• 10.1002/ijch.197600044

start page

• 247

end page

• 252

volume

• 15

issue

• 3-4

URL

• http%3A%2F%2Fdx.doi.org%2F10.1002%2Fijch.197600044