Synthesis and characterization of two new cadmium phosphonocarboxylates Cd-2(OH)(O3PC2H4CO2) and Cd-3(O3PC2H4CO2)(2)center dot 2H(2)O Academic Article

abstract

• The coordination chemistry of 2-carboxyethylphosphonic acid with cadmium salts is described, leading to two new pillared layered phosphonates that were fully characterized using 31P and 113Cd solid state NMR spectroscopy. A densely packed arrangement is observed for Cd2(OH)(O3PC2H4CO2), exhibiting structural features uncommon in metal phosphonates: a triply bridging OH, a (222) connectivity for the PO3 groups and a mixed 5-fold and 6-fold coordination for the metal.

authors

• Clearfield, Abraham

published proceedings

• JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS

author list (cited authors)

• Fredoueil, F., Evain, M., Massiot, D., Bujoli-Doeuff, M., Janvier, P., Clearfield, A., & Bujoli, B.

citation count

• 64

complete list of authors

• Fredoueil, F||Evain, M||Massiot, D||Bujoli-Doeuff, M||Janvier, P||Clearfield, A||Bujoli, B

publication date

• April 2002

publisher

• Royal Society of Chemistry (RSC)  Publisher

published in

• n1472-7773ISSN  Journal

keywords

• 34 Chemical Sciences
• 3402 Inorganic Chemistry
• Clinical Research

Digital Object Identifier (DOI)

• 10.1039/b110275n

start page

• 1508

end page

• 1512

volume

• 0

issue

• 7

URL

• http%3A%2F%2Fdx.doi.org%2F10.1039%2Fb110275n