MECHANISM OF ION-EXCHANGE IN ZIRCONIUM-PHOSPHATES .23. EXCHANGE OF 1ST ROW DIVALENT TRANSITION-ELEMENTS ON GAMMA-ZIRCONIUM PHOSPHATE Academic Article

abstract

• The exchange of transition metal (M2+) ions from manganese to zinc with -zirconium phosphate was examined. By using acetate salts the hydrogen ion concentration is kept low enough to achieve high loadings. The fully loaded solids have the composition ZrM(PO4)24H2O. Near quantitative uptakes are achieved at 100C. The interlayer spacings change very little with loading indicating that -zirconium phosphate is able to accomodate cations and water molecules without appreciable increase in volume. The copper exchanged phase readily forms an acetylacetonate when shaken with 2,4-pentanedione. 1978.

authors

• Clearfield, Abraham

published proceedings

• JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY

author list (cited authors)

• CLEARFIELD, A., & KALNINS, J. M.

citation count

• 37

complete list of authors

• CLEARFIELD, A||KALNINS, JM

publication date

• January 1978

publisher

• Elsevier  Publisher

published in

• Journal of Inorganic and Nuclear Chemistry  Journal

Digital Object Identifier (DOI)

• 10.1016/0022-1902(78)80258-9

start page

• 1933

end page

• 1936

volume

• 40

issue

• 11

URL

• http%3A%2F%2Fdx.doi.org%2F10.1016%2F0022-1902%2878%2980258-9