MORE ON CRYSTALLINE ZIRCONIUM PHOSPHATES
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abstract
Heating -zirconium phosphate (-ZrP) for long periods of time leads to the formation of two new phases -ZrP and -ZrP. The former phase is similar in structure to the phase obtained from solid-solid ion exchange reactions at low metal ion loadings. Refluxing -ZrP in 157 M H3PO4 results in the formation of -ZrP which is converted to -ZrP on longer refluxing. Neither of these phases is a good ion exchanger. Several additional zirconium phosphate phases prepared in a variety of ways are also reported. 1973.