PSEUDO-TETRAHEDRAL GEOMETRY IN THE COPPER(II) COMPLEX OF A NOVEL 18-MEMBERED TETRA-AZA-MACROCYCLIC LIGAND - X-RAY CRYSTAL AND MOLECULAR-STRUCTURE
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abstract
Condensation of acetone with bis-(1,4-diaminobutane)copper(II) perchlorate yields a purple product, [(5SR,10RS)-2,4,4,11,11,13-hexamethyl-1,5,10,14-tetra- azacyclo-octadeca-1,13-diene]copper(II) perchlorate, which has an unusual pseudo-tetrahedral geometry about CuII, as indicated by X-ray analysis.