Pseudo-tetrahedral geometry in the copper( II ) complex of a novel 18-membered tetra-aza-macrocyclic ligand; X -ray crystal and molecular structure
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Condensation of acetone with bis-(1,4-diaminobutane)copper(II) perchlorate yields a purple product, [(5SR,10RS)-2,4,4,11,11,13-hexamethyl-1,5,10,14-tetra- azacyclo-octadeca-1,13-diene]copper(II) perchlorate, which has an unusual pseudo-tetrahedral geometry about CuII, as indicated by X-ray analysis.
author list (cited authors)
Martin, J., Timmons, J. H., Martell, A. E., Rudolf, P., Clearfield, A., & Willis, C. J.