MECHANISM OF ION-EXCHANGE IN ZIRCONIUM-PHOSPHATES .21. INTERCALATION OF AMINES BY ALPHA-ZIRCONIUM PHOSPHATE Academic Article

abstract

• The intercalation of n-propylamine, n-butylamine and ethylenediamine by the layered compound -zirconium phosphate has been examined. Each of the amines forms a number of phases whose interlayer spacings are indicative of the orientation of the amines within the layers. At low uptakes of the n-alkyl amines, they appear to lie parallel to the layers. At higher contents a double layer forms with the carbon chain backbone roughly inclined at a 60 angle to the plane of the layer. A maximum of one n-alkyl amine molecule per phosphate group is intercalated. Half as much ethylenediamine is intercalated which constitutes the same number of amine-groups. The interlayer spacings indicate, however, that the ethylenediamine chain always lies parallel to the layer but in at least four different orientations, giving rise to as many phases. 1979.

authors

• Clearfield, Abraham

published proceedings

• JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY

author list (cited authors)

• CLEARFIELD, A., & TINDWA, R. M.

citation count

• 113

complete list of authors

• CLEARFIELD, A||TINDWA, RM

publication date

• January 1979

publisher

• Elsevier  Publisher

published in

• Journal of Inorganic and Nuclear Chemistry  Journal

Digital Object Identifier (DOI)

• 10.1016/0022-1902(79)80283-3

start page

• 871

end page

• 878

volume

• 41

issue

• 6

URL

• http%3A%2F%2Fdx.doi.org%2F10.1016%2F0022-1902%2879%2980283-3