Nature of hydrous zirconia and sulfated hydrous zirconia Academic Article uri icon

abstract

  • The structure of crystalline hydrous zirconias and their methods of formation are described. A mechanism for the hydrolytic polymerization of ZrIV to obtain the several forms of hydrous oxide is presented. The method by which sulfate ion binds to the surface of zirconia particles is explored. It is concluded that the superacidity of sulfated zirconia arises from the presence of isolated bisulfate groups acting in conjunction with strong adjacent Lewis acid sites. Thus, both Br√łnsted and Lewis acid sites are present in sulfated oxides. ¬© 1994.

altmetric score

  • 3

author list (cited authors)

  • Clearfield, A., Serrette, G., & Khazi-Syed, A. H.

citation count

  • 185

publication date

  • June 1994