MECHANISM OF ION-EXCHANGE IN ZIRCONIUM-PHOSPHATES .26. IRREVERSIBLE EXCHANGE OF ALKALINE-EARTH CATIONS Academic Article

abstract

• Ion exchange of alkali metal cations and Cu2+ with -zirconium phosphate has been found to be irreversible. This is attributed to strong site binding. The cations are coordinated by water molecules and negative lattice oxygens in a stable arrangement. Site binding is also suggested as an explanation for the failure to produce fully exchanged alkali metal cation phases when -zirconium phosphate is titrated with mixed metal chloride-metal hydroxide solutions. 1979.

authors

• Clearfield, Abraham

published proceedings

• JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY

author list (cited authors)

• CLEARFIELD, A., & DJURIC, Z.

citation count

• 12

complete list of authors

• Clearfield, Abraham||Djurić, Zora

publication date

• January 1979

publisher

• Elsevier  Publisher

published in

• Journal of Inorganic and Nuclear Chemistry  Journal

Digital Object Identifier (DOI)

• 10.1016/0022-1902(79)80285-7

start page

• 885

end page

• 887

volume

• 41

issue

• 6

URL

• http%3A%2F%2Fdx.doi.org%2F10.1016%2F0022-1902%2879%2980285-7