MECHANISM OF ION-EXCHANGE IN ZIRCONIUM-PHOSPHATES .26. IRREVERSIBLE EXCHANGE OF ALKALINE-EARTH CATIONS
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Ion exchange of alkali metal cations and Cu2+ with -zirconium phosphate has been found to be irreversible. This is attributed to strong site binding. The cations are coordinated by water molecules and negative lattice oxygens in a stable arrangement. Site binding is also suggested as an explanation for the failure to produce fully exchanged alkali metal cation phases when -zirconium phosphate is titrated with mixed metal chloride-metal hydroxide solutions. 1979.
JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY
author list (cited authors)
CLEARFIELD, A., & DJURIC, Z.
complete list of authors
Clearfield, Abraham||Djurić, Zora