Cs+-Selective Ion Exchange and Magnetic Ordering in a Three-Dimensional Framework Uranyl Vanadium(IV) Phosphate Academic Article uri icon

abstract

  • Cs+- selective ion exchange and magnetic ordering in a three-dimensional framework uranyl vanadium (IV) phosphate was studied. The synthesis of K [(UO2)(VO)4H1.52(PO 4)5] was achieved by reacting UO2(NO 3)2.6H2O with V metal phosphoric acid, and KCI under mild conditions. Confirmation of the +4 oxidation state for vanadium was provided by magnetic susceptibility measurements on Rb-UVP-2. This work provides further expansion of the structural building units that can be used to construct three-dimensional uranyl containing frameworks.

published proceedings

  • Chemistry of Materials

author list (cited authors)

  • Shvareva, T. Y., Skanthakumar, S., Soderholm, L., Clearfield, A., & Albrecht-Schmitt, T. E.

citation count

  • 69

complete list of authors

  • Shvareva, Tatiana Y||Skanthakumar, S||Soderholm, L||Clearfield, Abraham||Albrecht-Schmitt, Thomas E

publication date

  • January 2007