Cs+-selective ion exchange and magnetic ordering in a three-dimensional framework uranyl vanadium(IV) phosphate Academic Article

abstract

• Cs+- selective ion exchange and magnetic ordering in a three-dimensional framework uranyl vanadium (IV) phosphate was studied. The synthesis of K [(UO2)(VO)4H1.52(PO 4)5] was achieved by reacting UO2(NO 3)2.6H2O with V metal phosphoric acid, and KCI under mild conditions. Confirmation of the +4 oxidation state for vanadium was provided by magnetic susceptibility measurements on Rb-UVP-2. This work provides further expansion of the structural building units that can be used to construct three-dimensional uranyl containing frameworks.

authors

• Clearfield, Abraham

published proceedings

• CHEMISTRY OF MATERIALS

author list (cited authors)

• Shvareva, T. Y., Skanthakumar, S., Soderholm, L., Clearfield, A., & Albrecht-Schmitt, T. E.

citation count

• 70

complete list of authors

• Shvareva, Tatiana Y||Skanthakumar, S||Soderholm, L||Clearfield, Abraham||Albrecht-Schmitt, Thomas E

publication date

• January 2007

publisher

• American Chemical Society (ACS)  Publisher

published in

• CHEMISTRY OF MATERIALS  Journal

keywords

• 34 Chemical Sciences
• 3402 Inorganic Chemistry

Digital Object Identifier (DOI)

• 10.1021/cm062490l

start page

• 132

end page

• 134

volume

• 19

issue

• 2

URL

• http%3A%2F%2Fdx.doi.org%2F10.1021%2Fcm062490l